For an assessment of corrosion speed and mechanisms, different methods are used:
 
  • Electrochemical methods (current-density-potential-curves):
    • Determination of corrosion rates by Tafel extrapolation
    • Determination of pittingcorrosion potentials
    • Investigation of passivation behavior of high alloyed steels
    • Investigation of the sensitization of high alloyed steels (e.g. due to increased temperatures during welding processes)
  • Impedance spectroskopy for determination of the charge transfer resistance, electrolyte resistance and double layer capacity or capacities of surface layers, respectively
  • ageing experiments in electrolytes (or other corrosive atmosphere); determination of corrosion speeds by measurement of sample weight before and after experiments
  • Chemical analyses (EDX, XPS, AES, SIMS), for determination of corrosion products
  • Microscopical investigations (optical microscope, scanning electron microscope) e.g. of fracture surfaces after stress corrosion cracking or shapes of pittings after pitting corrosion
  • Wöhler curves in electrolytes (fatigue corrosion cracking)
In the case of more complex problems, it is possible to perform a literature research for receiving an overview on existing investigations and their results.
Investigation of corrosion